A novel ruthenium complex RuCl_2P(C_6H_5)_3_2-(R,R)-DPEN (DPEN=1,2-diphenylethylene- diamine) was synthesized and characterized by 1H and 31 P NMR. The ruthenium complex was applied to the asymmetric hydrogenation of acetonaphthone.

  • 合成了(R;R)-1;2-二苯基乙二胺((R;R)-DPEN)、钌和三苯基膦的三元配合物RuCl2[P(C6H5)3]2-(R;R)-DPEN;并将其用于萘乙酮的不对称加氢反应.
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