Atom Transfer Radical Polymerization (ATRP) of MMA initiated by cholesteryl chioroformate (CC) and catalyzed by CuCl/MA5-DETA was reported for the first time.

• 摘要首次报道以氯甲酸胆固醇酯(CC)为引发剂，氯化亚铜和自制MA5-DETA为催化剂进行甲基丙烯酸甲酯(MMA)的原子转移自由基聚合(ATRP)反应。