Combined Baylis-Hillman reaction condition with Ireland-Claisen rearrangement, we have established a novel DABCO-catalyzed Ireland-Claisen rearrangement of allylic acrylates.

• 将Baylis-Hillman反应条件与Ireland-Claisen重排反应有机结合起来，创建了一条新颖的DABCO-催化的丙烯酸烯丙酯类化合物的Ireland-Claisen重排反应路线；