Using the Simplified Transition State Theory (STST), the activation entropies and A factors of the title reactions have been first calculated according to the con-certed mechanism.
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- 用简化的过渡态理论(STST);按协同机制;对几种桥环化合物裂解反应的活化熵、A因子作了首次估算.;并和实验结果作比较讨论了反应可能进行的机理:解释了反应的A因子递变现象