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late transition metal complex 后过渡金属配合物
Progress of Late Transition Metal Complexes for Ethylene Oligomerization and Polymerization 后过渡金属配合物催化乙烯齐聚与聚合的研究进展
Organometallic chemistry of late transition metal complexes with boron analogs of cyclopentadienyl ligand; 类Cp配体后过渡金属配合物的合成及其金属有机化学性质研究;
Many different kinds of catalysts including heteropoly compound, transition metal complex, metalloporphyrin, metal phthalocyanines and other catalysts are summarized. 重点介绍了杂多化合物、过渡金属配合物、金属卟啉及金属钛菁等催化剂的催化效果。
This paper reviewed the progress in the studies on copolymerization of olefin with O|cotained polar monomers in the presence of Ziegler|Natta catalyst, metallocene catalyst and late transition metal catalyst. 综述了在齐格勒纳塔、茂金属和后过渡金属催化体系下 ,烯烃与含氧极性功能单体共聚的研究进展
The research progress on carbonylation reactions of heterocycles (such as epoxides and aziridines) during the last 40 years is reviewed in the presence of transition metal complex catalysts. 综述了近40年来杂环化合物和一氧化碳在金属络合物催化下的羰基化反应,详细讨论了不同类型反应的有关机理,并展望了该领域的研究前景。
the late transition metal catalyst 后过渡金属催化剂
Oxygen carrier is a kind of transition metal complexes which can absorb O2 reversibly. 化学链燃烧是一种新型的燃烧技术,氧载体的性能对它的发展非常重要。
During the last decade new hydrosilylation catalysts,predominantly homogenous and heterogenous transition metal complexes have been developed. 近年出现了许多新的硅氢加成反应催化剂,主要是指过渡金属化合物的均相和多相催化剂。
Keywords nickel diimine coordination complex;ethylene;methyl acrylate;late transition metal catalyst;copolymerization; 镍二亚胺配合物;乙烯;丙烯酸甲酯;后过渡金属催化剂;共聚合;
The structures, properties and synthesis of novel catalysts, salicvlaldimine transition metal complexes, for olefin polymerization were reviewed. 综述了用于烯烃聚合的新型单活性中心水杨醛亚胺过渡金属络合物催化剂的结构、合成方法和性能等。
During the last decade new hydrosilylation catalysts, predominantly homogenous and heterogenous transition metal complexes have been developed. 摘要近年出现了许多新的矽氢加成反应催化剂，主要是指过渡金属化合物的均相和多相催化剂。
Novel methods for the carbonylation are introduced of olefins,halides,paraffins,and arenes under ambient conditions and UV irradiation catalyzed by transition metal complexes. 介绍了以烯烃、卤代烃、烷烃及芳烃为底物,在光促进和温和条件下,用过渡金属催化进行羰基合成的新方法。
Keywords Norbornene;Late transition metal;Catalysts;Polymerization; 降冰片烯;后过渡金属;催化剂;聚合;
Transition metal complexes of hexamethylene tetramine are synthesized by solid state reaction and their thermochromism is investigated by TG-DSC spectra. 摘要研究了六次甲基四胺的过渡金属配合物的固相合成及其热色性。
The elementary principles and methods of carbon dioxide fixation by coordination and insertion reactions of transition metal complexes catalysis are reviewed. 摘要综述了利用过渡金属配合物和二氧化碳的配位及插入反应实现二氧化碳固定的基本方法、原理及其研究现状。
Keywords late transition metal catalyst;acenaphthenequinonediimine nickelous chloride complex;branched polyethylene;diethylaluminum chloride; 后过渡金属催化剂;苊二亚胺氯化镍配合物;支化聚乙烯;一氯二乙基铝;
Abstract: The elementary principles and methods of carbon dioxide fixation by coordination and insertion reactions of transition metal complexes catalysis are reviewed. 文摘:综述了利用过渡金属配合物和二氧化碳的配位及插入反应实现二氧化碳固定的基本方法、原理及其研究现状。
Recent advances in asymmetric hydrosilylation of prochiral carbonyl compounds catalyzed by chiral transition metal complexes are reviewed in this paper with 47 references. 评述了近年来手性金属配合物催化的前手性羰基化合物的不对称硅氢化反应研究进展。
Recent achievements in ethylene oligomerization by using transition metal complexes as catalysts are reviewed with emphases on the description of novel catalyst systems. 综述了水溶性膦配体的合成，以及水溶性过渡金属络合物催化剂在水／有机两相反应体系中催化剂反应的近期进展。