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- A novel ruthenium complex, [Ru(phen) 2CPIP](PF 6) 2, have been synthesized and characterized by EA, 1H NMR and ES-MS. 目的与方法合成了一种新型钌多吡啶配合物 [Ru(phen) 2 CPIP](PF6) 2 ,采用元素分析、核磁共振和电喷雾质谱对配合物进行表征 ,并采用电子吸收光谱和荧光光谱对配合物与DNA相互作用的性质进行研究。
- The 2, 6-pyridyl-diimine ruthenium complex exhibited good catalytic properties in the hydrogen transfer hydrogenation of ketones. 结果表明,这种吡啶二亚胺钌配合物对苯乙酮等的氢转移反应具有良好的催化性能。
- A novel ruthenium complex RuCl_2P(C_6H_5)_3_2-(R,R)-DPEN (DPEN=1,2-diphenylethylene- diamine) was synthesized and characterized by 1H and 31 P NMR. The ruthenium complex was applied to the asymmetric hydrogenation of acetonaphthone. 合成了(R;R)-1;2-二苯基乙二胺((R;R)-DPEN)、钌和三苯基膦的三元配合物RuCl2[P(C6H5)3]2-(R;R)-DPEN;并将其用于萘乙酮的不对称加氢反应.
- The antitumor activity, hydrolysis, binding characters to DNA and proteins of ruthenium complexes are briefly reviewed. 摘要本文对钌配合物在抗肿瘤方面的研究情况、水解过程、与DNA和蛋白质的作用情况进行了简要的评述。
- Metal complexes, especially ruthenium complexes, play a very important role in the field of medicine.The studies on the anticancer activity of ruthenium complex have make progress in last decades. 金属配合物在医药领域起着重要的作用,金属钌配合物在抗肿瘤活性研究方面取得了重要的进展。
- Based on the studies of authors' laboratory, the development of ruthenium complexes as anticancer drugs, as well as their possible anticancer mechanisms is reviewed. 结合本组的研究工作,本文对金属钌配合物在抗肿瘤活性以及抗肿瘤作用机制方面的研究进展进行了综述。
- Keywords substituted cyclopentadiene;ruthenium complex;chiral; 取代环戊二烯;钌配合物;手性;
- Mother and baby interact in a very complex way. 母亲与婴儿以非常复杂的方式相互影响。
- Keywords 2;6-pyridyl-diimine ruthenium complex;acetophenone;hydrogen transfer; 吡啶二亚胺钌配合物;苯乙酮;氢转移;
- Keywords ruthenium complex;organic synthesis;spectroelectrochemistry; 金属钌配合物;有机合成;光谱电化学;
- Keywords Aminophosphine ruthenium complex;Acetophenone;Hydrogenation; 胺膦钌配合物;苯乙酮;氢化;
- Keywords Polypyridyl ruthenium complex;DNA;Intercalation;Groove binding; 多吡啶钌配合物;DNA;插入作用;沟面结合;
- Some of them developed a great inferiority complex. 他们有些人养成了严重的自卑感。
- My grandmother has a complex against foreigners. 我奶奶对外国人抱有偏见。
- Keywords Ruthenium complex;Phosphine;Diamine;Hydrogenation;Aromatic ketones.A; 钌配合物;膦配体;二胺;加氢反应;芳基酮;
- Life is getting more complex and difficult. 生活正在变得越来越复杂和艰难。
- He has a complex about his weight. 他过分关心自己的体重。
- Complex, intricate, and involved. 复杂的、错综的和涉及的
- A petrochemical complex is to be built here. 这儿将建造一个石油化学联合企业。