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- ruthenium complex catalyst 钌络合物催化剂
- A novel ruthenium complex, [Ru(phen) 2CPIP](PF 6) 2, have been synthesized and characterized by EA, 1H NMR and ES-MS. 目的与方法合成了一种新型钌多吡啶配合物 [Ru(phen) 2 CPIP](PF6) 2 ,采用元素分析、核磁共振和电喷雾质谱对配合物进行表征 ,并采用电子吸收光谱和荧光光谱对配合物与DNA相互作用的性质进行研究。
- The 2, 6-pyridyl-diimine ruthenium complex exhibited good catalytic properties in the hydrogen transfer hydrogenation of ketones. 结果表明，这种吡啶二亚胺钌配合物对苯乙酮等的氢转移反应具有良好的催化性能。
- Vapour phase hydrogenation of furfural was employed to produce 2 methylfuran through a copper ammonia complex catalyst. 采用负载型铜氨络合物催化剂进行糠醛气相加氢制2甲基呋喃。
- Preparation of tetracarbonyl cobaltate sodium, an important homogeneous complex catalyst, was studied. 用红外光谱和碘量法定性、定量测定了四羰基钴钠均相络合催化剂的物化性能。
- The kinetic study of the homogenous solution hydrogenation of NBR using Rh Ru bimetallic complex catalyst has been carried out. 以铑 -钌 (Rh -Ru)双金属催化剂对丁腈胶 (NBR)进行均相溶液加氢动力学研究。
- Sodium citrate was used as a complex catalyst for the titanium trichloride to reduce insoluble azo dyes and pigments in acetonitrile-alcohol-water system. 本文提出了在乙腈-乙醇-水混合溶剂中以柠檬酸钠作络合剂,三氯化钛还原非水溶性偶氮染料和颜料。
- A novel ruthenium complex RuCl_2P(C_6H_5)_3_2-(R,R)-DPEN (DPEN=1,2-diphenylethylene- diamine) was synthesized and characterized by 1H and 31 P NMR. The ruthenium complex was applied to the asymmetric hydrogenation of acetonaphthone. 合成了(R;R)-1;2-二苯基乙二胺((R;R)-DPEN)、钌和三苯基膦的三元配合物RuCl2[P(C6H5)3]2-(R;R)-DPEN;并将其用于萘乙酮的不对称加氢反应.
- The antitumor activity, hydrolysis, binding characters to DNA and proteins of ruthenium complexes are briefly reviewed. 摘要本文对钌配合物在抗肿瘤方面的研究情况、水解过程、与DNA和蛋白质的作用情况进行了简要的评述。
- Trimethylaluminum(TMA),usually used in organic catalysis and organic synthesis,was synthesized by reaction of triethylaluminium (TEA) with methyl bromide on iron-stibonium complex catalyst. 用新的催化体系(铁-锑复合催化剂)催化三乙基铝(TEA)与溴甲烷进行烷基交换反应合成三甲基铝(TMA)。
- The cellulose oxyphosphine palladium complex catalyst was prepared and the catalytic activity of catalyst in the cross - coupling reaction of tributyltin hydride with acid chlorides was investigated. 制备了纤维素氧瞵-钯配合物催化剂,详细考察了催化剂对三(正)丁基锡氢化物和酰卤化合物偶联反应的催化作用。
- Based on the studies of authors' laboratory, the development of ruthenium complexes as anticancer drugs, as well as their possible anticancer mechanisms is reviewed. 结合本组的研究工作，本文对金属钌配合物在抗肿瘤活性以及抗肿瘤作用机制方面的研究进展进行了综述。
- The oxidative carbonylation of phenol to DPC catalyzed by palladium complexes catalyst system (PdCl2+ Cu(OAc)2+ TBAB+ H2BQ) has been studied. 开发出了苯酚氧化羰基化直接合成碳酸二苯酯钯系络合物催化体系：PdCl_2+Cu(OAc)_2+TBAB+H_2BQ；
- Metal complexes, especially ruthenium complexes, play a very important role in the field of medicine.The studies on the anticancer activity of ruthenium complex have make progress in last decades. 金属配合物在医药领域起着重要的作用,金属钌配合物在抗肿瘤活性研究方面取得了重要的进展。
- A kind of complexing catalyst was introduced.The influences of the amount of complexing catalyst, temperature and time on the esterification reaction were investigated. 提出了一种复合催化剂,讨论了催化剂用量、反应温度、反应时间三因素对酯化反应的影响。
- coordination catalyst, complex catalyst 络合催化剂
- double metal cyanide complex catalyst 双金属氰化络合物催化剂
- A new method to fabricate polymer-dispersed liquid crystal (PDLC) films adopting complex catalysts system was devised. 摘要提出一种采用复合催化剂体系制备聚合物分散液晶(PDLC)膜的新方法。
- Keywords substituted cyclopentadiene;ruthenium complex;chiral; 取代环戊二烯;钌配合物;手性;
